Oxygen-deficient TiO2−x interlayer enabling Li-rich Mn-based layered oxide cathodes with enhanced reversible capacity and cyclability

The unique anion redox mechanism of Li-rich Mn-based layered oxide (LMLO) cathodes endows them with a higher specific capacity compared with conventional cathodes. However, the irreversible anion redox reactions can cause structural degradation and sluggish electrochemical kinetics in the cathode, resulting in a poor electrochemical performance in the batteries. Thus, to address these issues, a single-sided conductive oxygen-deficient TiO2−x interlayer was applied on a commercial Celgard separator as a coating layer towards the LMLO cathode. After coating TiO2−x, the initial coulombic efficiency (ICE) of the cathode increased from 92.1% to 95.8%, the capacity retention improved from 84.2% to 91.7% after 100 cycles, and the rate performance of the cathode was significantly enhanced from 91.3 mA h g−1 to 203.9 mA h g−1 at 5C. Operando differential electrochemical mass spectroscopy (DEMS) showed that the coating layer could restrain the release of oxygen in the battery, especially from the initial formation process. The X-ray photoelectron spectroscopy (XPS) results demonstrated that the favorable oxygen absorption by the TiO2−x interlayer benefitted the suppression of side reactions and cathode structural evolution and favored the formation of a uniform cathode-electrolyte interphase on the LMLO cathode. This work provides an alternative path to address the issue of oxygen release in LMLO cathodes.


Introduction
Lithium-ion batteries (LIBs) have gained increasing attention as efficient and clean energy storage devices to reduce the carbon dioxide emissions from fossil fuels, restraining environmental pollution, 1 and thus the related LIB industry has developed rapidly. 2,3 To date, LIBs have been widely applied in portable electronic devices, power tools, medical devices, smart watches, satellites, drones, marine vehicles, electric vehicles and utilityscale storage. However, the expanding applications of LIBs has also increased the battery requirements including higher energy density, longer life, lower cost, and safer features. 4 In the current commercial LIBs, the cathodes have a much lower specic capacity than anodes and are 40% of the cost of the whole battery, which limits the development of next-generation LIBs. 5 Beneting from their unique anion redox mechanism, 6 Li-rich Mn-based layered oxide (LMLO) cathodes can deliver a high specic capacity of more than 250 mA h g −1 , and thus are considered promising cathode candidates for next-generation high-energy-density LIBs. 7 However, LMLO cathode materials are associated with some critical issues, which should be resolved before their large-scale commercial applications, such as release of oxygen, voltage decay, and poor rate capability. 8 Generally, the Li 2 MnO 3 component in LMLO can be activated at 4.5 V with the concomitant release of oxygen during the rst charge process. 9,10 The release of oxygen leads to the degradation of the electrode structure from layer to spinel and aggravates the electrolyte decomposition on the surface of the electrode, resulting in poor cycle stability. 11 In addition, oxygen and oxygen radicals generated during charge/discharge have a negative inuence on the safety of batteries. 12 Recently, many different strategies have been proposed to solve the issue of oxygen release in LMLO cathodes. For example, doping was performed to stabilize the crystal structure and reduce the release of oxygen. 13 Also, a concentration gradient structure of LMLO was designed to increase the stability of the structure and avoid unexpected surface reactions to reduce oxygen release. 14 In addition, various materials, such as oxides, 15 phosphates, 16 uorides, 17 lithium-ion conductors, 18 polymers, 19 and functionalized coatings containing oxygen vacancies, were coated on the cathode to inhibit oxygen release by reducing side reactions. 20,21 However, doping with foreign elements and/or coating with inert compounds may reduce the capacity, and even reduce the conductivity of the material and diminish the rate capability. 21 In addition, both methods involve complex modication processes, which possibly destroy the surface structure of the cathode materials.
Modication of the separator is also commonly employed to improve the electrochemical performance of LIBs. Although the separator interlayer inevitably reduces the energy density of the whole battery, the improvement in electrochemical performance, thermal stability and safety performance by the interlayer of separator have attracted increasing attention from researchers. 22,23 Accordingly, researchers have investigated various coatings on the separator to improve the electrolyte wettability and thermal stability of the battery. 24,25 Parikh et al. developed a binary ceramic coating consisting of Al 2 O 3 and TiO 2 on a thin separator to enhance the thermal stability, thermal conductivity and electrolyte wettability. 26 Qi et al. proposed a mesoporous SiO 2 (mSiO 2 )-anchored separator via covalent bonding, where the mSiO 2 nanoparticles facilitated the storage of more electrolyte and enhanced the swi lithium-ion diffusion during charge/discharge. 27 However, this type of ceramic coating layer on the separator is generally designed to enhance the electrolyte wettability, thermal stability and mechanical properties, 28 and there is no report to date on modied separators that can store the oxygen released from LMLO during charge and discharge.
Black titanium dioxide (TiO 2−x ) has been widely applied in fuel cells, photoelectrochemical sensors and microwave absorbers. 29 TiO 2−x is a member of the homologous series known as Magneli phases, 30 where the substoichiometric titanium oxides consist of two-dimensional chains of octahedral TiO 6 , with the oxygen atom missing in every nth layer to compensate for the loss of stoichiometry. 31 This structure ensures the excellent electrical conductivity and great corrosion resistance of TiO 2−x materials. 32,33 In addition, TiO 2−x has good electrochemical stability in corrosive media (including organic electrolytes). 34 Furthermore, TiO 2−x has been applied as the separator coating layer of lithium-sulfur batteries due to its high affinity for polysuldes. 35,36 However, the use of TiO 2−x as a functional interlayer to absorb the oxygen evolved from highenergy cathodes (e.g., LMLO and high-nickel cathodes) has not been reported. The evolution of oxygen is the key issue hindering the commercialization of LMLO cathode materials. As mentioned previously, oxygen evolution can cause structural degeneration, voltage decay and electrolyte decomposition, which can result in inferior electrochemical performances in LMLO.
In this work, we proposed the use of oxygen-decient TiO 2−x as an interlayer to suppress the oxygen release of LMLO for the rst time. As shown by the schematic in Fig. 1, Li + and oxygen are liberated from the cathode during the charge process and migrate to the anode. The oxygen vacancies in the TiO 2−x interlayer adsorb the released oxygen, while Li + migrates to the anode. In addition, the porous structure of the coating layer on the separator facilitates the adsorption of oxygen without the hindrance of lithium-ion transportation. Consequently, this TiO 2−x interlayer improved the initial coulombic efficiency and enhanced the cyclability of the LMLO cathode due to its oxygen absorption effect and the mitigated side reactions between oxygen radicals and the electrolyte.

Materials
Polypropylene (PP) separators (Celgard 2400, thickness of ∼25 mm) were purchased from Nanjing MJS Energy Technology Co. Ltd. Black titanium dioxide powder was purchased from Shanghai TaiYang Technology Co. Ltd. and milled at 200 rpm for 8 h for subsequent use. The LMLO cathode powder was obtained from Ningbo Fuli Battery Material Technology Co. Ltd. The electrolyte containing 1 M LiPF 6 dissolved in uoroethylene carbonate/dimethyl carbonate (FEC/DMC 1/3 by volume) was provided by Suzhou DoDoChem Technology Co., Ltd.

Preparation of TiO 2−x -coated separator
The black titanium dioxide (TiO 2−x )-coated separator was prepared via the slurry coating method using polyvinylidene uoride (PVDF) as the binder. Firstly, TiO 2−x powder and PVDF were mixed at a mass ratio of 9 : 1 in N-methyl-2-pyrrolidone (NMP) with a solid content of about 35 wt%. Then, the slurry was coated on one side of the Celgard 2400 separator via doctor blading and dried at 60°C for 12 h in a vacuum drying oven. The as-prepared separators were punched into discs with a diameter of 19 mm. The TiO 2−x -coated separators with different thickness were denoted as TiO 2−x -1, TiO 2−x -2, TiO 2−x -3, and TiO 2−x -4, corresponding to the TiO 2−x loading of about 0.6, 1.1, 1.5, and 2 mg cm −2 , respectively.

Preparation of LMLO cathode electrode
The LMLO cathode material, Super-P and PVDF were mixed at a mass ratio of 85 : 10 : 5 and dispersed in NMP solvent in a Thinky mixer. The mixed slurry was coated on carbon-coated aluminum foil using a doctor blade and dried at 80°C in a vacuum drying oven overnight. The dried electrode was punched into discs with a diameter of 12 mm for electrochemical testing, and the active loading of each disc was about 4.5 mg.

Electrochemical measurements
CR2032-type coin cells were assembled using a cathode electrode, separator and lithium metal in an argon-lled glove box (O 2 < 0.5 ppm, H 2 O < 0.5 ppm). 1 M LiPF 6 dissolved in FEC/DMC (1/3 vol%) was used as the electrolyte. The cyclability and rate capability of the coin cells were evaluated using a NEWARE workstation (NEWARE, China) at 25°C in an incubator. For cyclability testing, the batteries were charged and discharged at 0.1C (1C = 250 mA g −1 ) for 2 cycles for the activation process, and then increased to 0.2C for subsequent cycles in the voltage range of 2-4.8 V. Electrochemical impedance spectroscopy (EIS) was carried out on an electrochemical workstation (Biological VMP3, France) in the range of 100 kHz to 10 mHz at an amplitude of 10 mV. Linear sweep voltammograms (LSV) were also investigated on the Biological VMP3 with a scan rate of 1 mV s −1 in the voltage range of the open circuit voltage to 5.2 V. Differential electrochemical mass spectroscopy (DEMS, Hiden Analytical, England) analysis was performed using a commercial ECC-DEMS in situ cell on an HPR-40 system. The cell was assembled in a glovebox. The cathode electrodes were prepared by mixing the active materials, Super-P and PVDF in the mass ratio of 85 : 10 : 5, and the total loading of the electrode was about 9 mg cm −2 . Lithium metal was used as the counter electrode. The electrolyte was the same as that used in the cointype cell. A Celgard 2400 separator and TiO 2−x -coated Celgard 2400 separator were employed for comparison. The inert carrier gas was argon with a ow rate of 0.5 mL min −1 . For electrochemical tests, the DEMS cell was evaluated using a LAND battery test system, which was charged and discharged at 0.1C in the voltage range of 2.0-4.8 V at 25°C.

Characterization
The X-ray diffraction (XRD, Rigaku Ultimate IV, Japan) patterns of the samples were collected using a powder X-ray Cu Ka radiation diffractometer (l = 1.5418 Å) at a scan rate of 5°min −1 . The morphology of the TiO 2−x powder and the separator were observed by scanning electron microscopy (SEM, Zeiss Sigma 300, Germany) and high-resolution transmission electron microscopy (HRTEM, JEM2100F, Japan). The element states of the samples were determined by X-ray photoelectron spectroscopy (XPS, Thermo Scientic ESCALAB 250Xi, USA) with an Al Ka source.

Results and discussion
As shown in Fig. 2a, the X-ray diffraction (XRD) patterns of the TiO 2−x powder can be mostly assigned to the standard PDF card (PDF#50-0787) of Ti 4 O 7 , 37 which is a member of Ti n O 2n−1 with super electrochemical stability and electrical conductivity. Besides, the other weak peaks are identied as that of the anatase TiO 2 phase (PDF#21-1272). As shown by the scanning electron microscopy (SEM) images in Fig. S1a and b, † the TiO 2−x powder has an irregular shape and contains 1-2 mm particles and 200-300 nm polyhedral particles. The high-resolution transmission electron microscopy (HRTEM) images used to characterize the crystal structure of the TiO 2−x particles, as shown in Fig. 2b, demonstrate the regular spacing distance of 0.33 nm for the observed planes, which can be assigned as the (1 20) crystal plane of the main component Ti 4 O 7 based on their dspacings. 38,39 The top and cross-section morphology of the Celgard 2400 separator and TiO 2−x -2-coated separator are demonstrated in Fig. 3. The inset images of Fig. 3a and d show that the Celgard 2400 separator is white, while the TiO 2−x -coated separator is black with the TiO 2−x interlayer well attached on one side of the Celgard 2400 separator with the adhesion of the PVDF binder. As shown in Fig. 3b, the spindle-shaped holes in the Celgard 2400 separator were produced by uniaxial tensile, 27 while the TiO 2−x -coated separator was uniformly covered by TiO 2−x particles. In addition, it can be seen from the crosssection morphology that the thickness of the Celgard 2400 separator is 25 mm and the coating layer is about 9 mm, corresponding to the TiO 2−x loading of about 1.1 mg cm −2 . The porous structure of the TiO 2−x -coated separator is clearly shown in Fig. 3d-f. This porous structure in the separator provides channels for the transportation of lithium ions together with the enhanced electrical conductivity due to the favourable conductivity of TiO 2−x . 34 More importantly, the porous structure has a large surface area and can effectively improve the oxygen adsorption efficiency.
To investigate the effect of the TiO 2−x interlayer on the electrochemical performance of the LMLO cathode, the coated Celgard 2400 separators with different TiO 2−x loadings were assembled with an LMLO cathode and Li-metal anode in CR2032-type coin cells. The coin cells were charged and discharged at 0.1C for the rst two cycles, followed by 0.2C for cyclability testing. Fig. 4a shows the initial charge and discharge curves of the batteries with pristine and TiO 2−x -coated Celgard 2400 separators. All the batteries demonstrated the typical features of LMLO materials, namely, a sloping region below 4.4 V, followed by a high voltage plateau at around 4.5 V during the rst charge process. The initial coulombic efficiency (ICE) and the discharge capacity of the LMLO cathode with the pristine Celgard 2400 separator was 92.1% and 303.0 mA h g −1 , while that for the TiO 2−x -1, TiO 2−x -2, TiO 2−x -3 and TiO 2−x -4 samples was 95.5%, 95.5%, 95.8%, and 95.3%, and their initial discharge capacities were 306.8 mA h g −1 , 308.9 mA h g −1 , 306.2 mA h g −1 , and 308.2 mA h g −1 , respectively. The ICE of the LMLO cathode with the TiO 2−x -coated separators was signicantly enhanced compared with the pristine Celgard 2400 separator. Moreover, the discharge capacity of the cathodes with the TiO 2−x -coated separators also increased slightly compared with that with that of the pristine Celgard 2400 separator. The higher ICE and discharge capacity demonstrate the excellent reversibility of the LMLO cathode, which is due to the inhibition of oxygen release by the TiO 2−x interlayer and favorable Li-ion transport rate. In addition, the charge and discharge curves of the cathode with the pristine Celgard 2400 separator and TiO 2−x coated separators almost overlapped, which indicates that the TiO 2−x -coated interlayer improved the reversibility of the electrode, while it did not participate in the lithium deintercalation and electrochemical reaction. As shown in Fig. 4b, the batteries with the TiO 2−x -coated separator exhibited a similar cycling performance in the rst 10 cycles as that with the pristine Celgard 2400 separator. However, with an increase in the cycle number, the discharge capacity of the battery with the pristine Celgard 2400 separator decreased rapidly. In contrast, the discharge capacity of the battery with the TiO 2−x -coated separator was stable. Aer 100 cycles, the cycle retentions of the LMLO cathodes with the Celgard 2400, TiO 2−x -1, TiO 2−x -2, TiO 2−x -3 and TiO 2−x -4 separators were 84.2%, 90.6%, 91.7%, 91.5%, and 90.7%, respectively. In addition, the batteries with the TiO 2−x -coated separator exhibited lower average voltage attenuation than that with the pristine Celgard 2400 separator. As shown in Fig. 4c, the voltage of the batteries with the coated separator similarly decreased to 3.1271 V aer 100 cycles, which is higher than 3.1025 V for the battery with the pristine Celgard 2400 separator. The electrochemical performances of the batteries indicate that the separators with different TiO 2−x loadings all effectively enhanced the ICE and cycle stability of the LMLO cathode compared to the Celgard 2400 separator.
The TiO 2−x -coated separator also enhanced the battery rate performance when the batteries were charged at 0.1C and discharged under different rates from 0.1C to 5C, and nally back to 0.1C. As shown in Fig. 4d, the battery with the TiO 2−x -2 separator exhibited a better performance than that with the TiO 2−x -1, TiO 2−x -3 and TiO 2−x -4 separators and delivered the specic discharge capacities of 305.9, 288.9, 274.4, 262.3, 245.5, 230.9 and 203.9 mA h g −1 at 0.1C, 0.2C, 0.5C, 1C, 2C, 3C and 5C  rate, respectively. These results are higher than that of the battery with the pristine Celgard 2400 separator, i.e., 304.8, 286.4, 271.3, 258.5, 238.8, 209.1, and 91.3 mA h g −1 under the same rate testing condition. When the rate returned to 0.1C, the discharge capacities mostly recovered for all the batteries. The corresponding discharge curves of the cathode with the pristine Celgard 2400 and TiO 2−x -2 separators at different rates are demonstrated in Fig. 4e and f, respectively. The battery with the pristine Celgard 2400 exhibited a higher polarization and lower discharge capacity than that with the TiO 2−x -2 separator. The enhanced rate performance of the battery with the TiO 2−x -2 separator can be ascribed to the superior electrical conductivity of the TiO 2−x coating layer. 40 The gas evolution during the rst charge/discharge of the cathode with different separators was analysed by operando differential electrochemical mass spectroscopy (DEMS). The effect of the TiO 2−x coating layer on the gas evolution was evaluated by analysing the evolution of O 2 and CO 2 . The voltage curves and the gas partial pressure were examined in commercial ECC-DEMS cells, as shown in Fig. 5, where the baseline of the gas partial pressure was removed to eliminate the inuence of the environment. 41 As shown in Fig. 5b, the O 2 evolution appeared at the end of the charge process due to the irreversible evolution of lattice oxygen, which is consistent with the literature. 42 The release of O 2 in the battery with the TiO 2−x -2-coated separator was signicantly weaker than that in the battery with the pristine Celgard 2400 separator, benetting from the positive effect of the TiO 2−x interlayer on the oxygen absorption and reduced side reactions. The CO 2 evolution, as shown in Fig. 5c, shows two waves for the battery with the pristine Celgard 2400 separator. The rst wave of CO 2 evolution at around 4.5 V is due to the decomposition of the alkyl carbonate solvent. 6 The second wave of CO 2 evolution appeared at the end of the charge, arising from the interaction between the electrolyte solvent and the LMLO lattice. 43 Conversely, there was almost no CO 2 wave at 4.5 V for the battery with the TiO 2−x -2 separator, which may be due to the expanded electrochemical stability window induced by the TiO 2−x coating. As demonstrated by the linear sweep voltammetry (LSV) measurement of the cells containing a stainless steel working electrode and lithium foil counter/reference electrode in Fig. S2, † the electrochemical anodic stability of the electrolyte (1 M LiPF 6 in FEC/ DMC (1/3 vol%) for TiO 2−x ) was greatly improved by the TiO 2−x coating. In addition, the CO 2 evolution from the battery with the TiO 2−x -2 separator was signicantly weaker than that from the battery with the pristine Celgard 2400 separator, which can be attributed to the mitigated side reactions between the electrolyte solvent (FEC) and LMLO lattice due to the TiO 2−x coating layer. The behaviour of O 2 and CO 2 evolution shows that the TiO 2−x coating layer could absorb the oxygen released from LMLO and restrain the side reactions between LMLO and the electrolyte. 44 The effect of TiO 2−x coating layer on the interfacial resistance and charge transfer kinetics during battery cycling was investigated by electrochemical impedance spectroscopy (EIS). The EIS results of the LMLO‖Li batteries aer 5 and 100 cycles are exhibited in Fig. 6a and b, respectively. The equivalent circuit of the Nyquist plots for the activated and cycled batteries consist of two semicircles at high and medium frequencies and a short straight line at low frequency, respectively. The high frequency semicircle is associated with the surface lm resistance (R sf ) and the medium frequency semicircle is associated with the charge transfer resistance (R ct ). The Nyquist plots are tted with the equivalent circuit model in the inset image in Fig. 6a and the tting values of EIS are demonstrated in Table  S1. † Obviously, the battery with the pristine Celgard 2400 separator demonstrated a higher R sf compared with the batteries with the TiO 2−x -coated separators aer 5 cycles. The R ct of the battery with the pristine Celgard 2400 separator is slightly higher than that of the batteries with the TiO 2−x -coated separators. The R sf of the battery with the pristine Celgard 2400 separator improved from 24.2 U aer 5 cycles to 28.2 U aer 100 cycles, which is attributed to the side reactions during the cycle process on the electrode surface. The R sf of the batteries with the TiO 2−x -2 and TiO 2−x -3 separators aer 100 cycles slightly decreased compared with that aer ve cycles, which can be ascribed to the adsorption of oxygen and inhibition of electrolyte decomposition due to the TiO 2−x coating layer during cycling. The evolution of R ct upon cycling can explain the high stability and excellent rate performance of the battery with the TiO 2−x -2 separator. The R ct of the battery with the TiO 2−x -2 separator increased from 23.8 U in the 5th cycle to 65.5 U in the 100th cycle, while the battery with the pristine Celgard 2400 separator presented a greater increase from 29.2 U to 174.7 U under the same testing condition. The value of R sf slightly increased from 18.0 U to 22.3 U and the R ct signicantly increased from 20.2 U to 162.3 U aer 100 cycles for the batteries with TiO 2−x -1, which can be attributed to the insufficient inhibition of side reactions and oxygen absorption effect by the thin TiO 2−x interlayer. In the case of the battery with the TiO 2−x -4 separator, the R sf increased from 20.3 U to 30.0 U and R ct increased from 28.7 U to 155.2 U aer 100 cycles due to the thicker TiO 2−x interlayer with a porous structure, which may facilitate the absorption of more electrolyte and higher Li-ion tortuosity than the TiO 2−x -2 sample. However, it is worth noting that although the total impedance values of the batteries with TiO 2−x -1 and TiO 2−x -4 increased signicantly aer 100 cycles, their impedance values were still smaller than the battery with the Celgard 2400 separator. Besides, the batteries with TiO 2−x -1 and TiO 2−x -4 demonstrated a higher capacity retention than the battery with the Celgard 2400 separator due to the positive effect of the TiO 2−x interlayer on the enhancement of LMLO cathode structure stability during long cycles. Combined with the O 2 and CO 2 evolution results, the variation in R sf and R ct also indicates that the TiO 2−x coating layer inhibited the release of oxygen and restrained the side reaction on the LMLO electrode.
To evaluate the process of oxygen adsorption, the chemical states of titanium and oxygen in the TiO 2−x coating layer upon charge/discharge were detected by XPS. The TiO 2−x -coated separators were obtained by disassembling coin-cells in the charged and discharged states in an Ar-lled glovebox. The O 1s and Ti 2p XPS spectra of the fresh TiO 2−x -coated separator and that in the charged and discharged states from the rst cycle are shown in Fig. 7a and b. As shown in Fig. 7a, the tted peaks located at about 531.6 eV, 530.8 eV and 529.4 eV correspond to absorbed oxygen, oxygen vacancy and lattice oxygen, respectively. [45][46][47][48] In the case of the fresh TiO 2−x -coated separator, oxygen vacancies and lattice oxygen in are present in the O 1s spectra. Aer charging to 4.8 V, the intensity of the oxygen vacancy peak decreased and adsorbed oxygen appeared, indicating that the TiO 2−x coating layer adsorbed the oxygen released from the LMLO lattice. 49 The intensity of the adsorbed oxygen peak decreased and the intensity of the oxygen vacancy peak increased aer discharge, indicating that some of the absorbed oxygen desorbed during discharge, which may be inuenced by the electric eld. 50,51 Fig. 7b shows the presence of Ti 4+ and Ti 3+ in the Ti 2p spectra with the binding energy of Ti 3+ lower than that of Ti 4+ , and the existence of Ti 3+ conrms the presence of oxygen vacancies in TiO 2−x . 40 The contents of Ti 3+ and Ti 4+ were semi-quantitatively analysed by tting the XPS results. The contents of Ti 3+ for the fresh TiO 2−x -coated separator and that in the charged and discharged states were determined to be 42.76%, 34.23%, and 41.28%, respectively. The excess electrons produced by the existence of oxygen vacancies could freely hop at room temperature to balance the valence states. [52][53][54] These results demonstrate that the content of Ti 3+ decreased during the battery charging process, and subsequently increased during the discharging process, which correspond to the changes in absorbed oxygen and oxygen vacancies. In addition, powder XRD was performed to investigate the possible phase changes in the crystal structure of the TiO 2−x coating layer on the separator during the charge and discharge process. As shown in Fig. S3, † the XRD patterns of the fresh TiO 2−x -coated separator and that in the charged and  discharged states are very similar, suggesting that there are no great or slight changes in the crystal structure of the TiO 2−x coating layer during charging and discharging.
To deeply understand the structural evolution during the rst charge/discharge process of the LMLO cathode and the inuence of the TiO 2−x interlayer on the ICE of the LMLO cathode, ex situ XRD was conducted on the LMLO cathodes disassembled from the cells with a Celgard 2400 separator and with TiO 2−x -coated separator at different charge/discharge potentials. 55 The ex situ XRD patterns of the two samples between 10°to 45°during the rst charge and discharge process are shown in Fig. S4. † 56 As shown in Fig. 8a and b, the (003) and (104) diffraction peaks representing the lattice parameters c and a are magnied to observe the change in lattice parameters during the rst charge and discharge. The LMLO crystal is arranged by periodic Li layers or transition metal (TM) layers and oxygen layers. The (003) diffraction peak corresponds to the [001] crystal direction, c represents the lattice distance between the oxygen layer and Li layer or TM layer, and a represents the lattice parameter of the crystal plane composed of lithium, TM and oxygen. 57 During the rst charge process, the (003) peak shied to a lower angle before the charge plateau due to the removal of lithium and the increased electrostatic repulsion between the oxygen layers. Then, the (003) peak shied to a higher angle during the charge plateau due to the activated Li 2 MnO 3 and release of oxygen. 58 It was found that the changes in the (003) peak in the LMLO cathode with the Celgard 2400 separator and with TiO 2−x -coated separator during the rst charge process are similar. During the rst discharge process, similar to previous reports in the literature, the lithium ions moved to the opposite direction, the (003) peak moved to a higher angle rstly, and then to a lower angle, which is contrary to the trend during the charge process. 57 However, it can be distinguished by comparing the two samples that the (003) peaks of the LMLO cathode with TiO 2−x separator exhibited a greater shi to a lower angle than that of the LMLO cathode with the Celgard 2400 separator, especially at a low potential before the end of the discharge. These results are probably caused by the higher reversible anion redox due to the TiO 2−x interlayer, 59 leading to extra capacity in the low potential region (Fig. 4a). 60 In addition, the (104) peak shied to a higher angle during the rst charge process, and then moved to a lower angle during the rst discharge process, which is related to the extraction/insertion of lithium ions and the migration of TM ions. 57 The LMLO cathode with the TiO 2−x -coated separator had a smaller angle shi of the (003) and (104) diffraction peaks at the end of discharge than the LMLO cathode with the Celgard 2400 separator due to the improved reversibility during the rst charge and discharge. 61 To understand the inuence of the TiO 2−x interlayer on the structural evolution of the LMLO cathode during the cycling process, the coin cells aer 100 cycles were disassembled to compare the XRD patterns of the LMLO cathode with the Celgard 2400 separator and that with the TiO 2−x -coated separator. As shown in Fig. S5, † the crystal structure of both LMLO cathodes degraded compared with the fresh LMLO electrode. The split peaks of (006)/(102) demonstrate the ordered layered structure, and the lower intensity ratio of (003) and (104) exhibit the higher cation mixing. 21 The careful observation of I (003) /I (104) shows that the cathode with the TiO 2−x -coated separator it matched the fresh LMLO cathode, but was higher than the cathode with the Celgard 2400 separator. In addition, the split peaks of (006)/(102) in the LMLO cathode with the TiO 2−xcoated separator were noticeable, while that in the LMLO cathode with the Celgard 2400 separator was almost indistinguishable, which may be caused by the devastating release of oxygen. 62 These results indicate that the TiO 2−x -coated separator mitigated the release of oxygen and improved the stability of the LMLO crystal structure compared to the cathode with the Celgard 2400 separator.
The cycled cathodes with different separators were characterized by XPS to analyse the inuence of the TiO 2−x interlayer on the CEI of the LMLO cathodes. The tted peaks in C 1s ( Fig. 9a and e) and O 1s (Fig. 9b and f) of C]O and C-O are attributed to the decomposition of carbonate and side reactions. By comparing the two samples, there were more C]O and C-O species on the cathode with the Celgard 2400 separator than the cathode with the TiO 2−x -2 separator. In addition, the cathode with the Celgard 2400 separator demonstrated more Li 2 CO 3 on its surface according to the O 1s spectra, which is harmful to the cathode. 63 According to the F 1s spectra in Fig. 9c and g and P 2p spectra in Fig. 9d and h, both samples contained Li x PF y and Li x PO y F z , which is attributed to the decomposition of LiPF 6 during cycling. 21 However, the cathode with the Celgard 2400 separator exhibited more TM-F and Li-F species, which may be derived from the strong reactions between the LMLO lattice and the electrolyte. To demonstrate the inuence of the   Fig. S6, † the LMLO cathode with the Celgard 2400 separator exhibited a discontinuous and nonuniform CEI, while the LMLO cathode with the TiO 2−x -2 separator exhibited a continuous CEI with a thickness of about 4 nm, which is thinner and more uniform than that on the LMLO cathode with the Celgard 2400 separator. In addition, Fig. 10 demonstrates the structural decay of the cycled cathodes with the Celgard 2400 and TiO 2−x -2 separators. Fig. 10a shows that there are plenty rock-salt structure domains in the surface region, and many voids and spinellike structures in the inner region together with a few layered structures. In contrast, as shown in Fig. 10b, spinel-like structure domains appeared near the surface and the layered structure was well-maintained in the inner regions due to the absorption of oxygen and inhibition of side reactions by the TiO 2−x interlayer.
Considering the potential effect of the electrochemical shuttle on the cell components, 64 the morphology and composition of the Li anode-faced sides of the separator may be valuable to analyze the effect of the TiO 2−x interlayer and cathode stability. 65 Fig. S7a † shows that a part of the SEI remained on the surface of the Celgard 2400 separator with large broken Li dendrites embedded in the separator, while the surface of the Li anode-faced side of the TiO 2−x -coated separator (Fig. S7b †) appeared smoother and had a much smaller quantity of particles. In the XPS spectra shown in Fig. S8, † the products of carbonate decomposition and Li oxide were observed on the Li anode-faced side Celgard 2400 separator, while many Li uoride components were observed on the Li anode-faced side TiO 2−x -2 separator. The aforementioned results further indicate that the TiO 2−x coating layer on the separator prevented the occurrence of excessive side reactions and enhanced the cathode stability, which can be attributed to the absorption of oxygen on the TiO 2−x coating layer, preventing oxygen and oxygen radicals from crossing the separator and enhancing the electrochemical stability at a high voltage. To determine the inuence of the TiO 2−x coating layer on the impedance of the cathode and anode electrodes, a threeelectrode assembly was used to demonstrate the resistance of the LMLO cathode and Li anode separately. 66 As shown in Fig. S9, † the impedance of the three-electrode was roughly consistent with the EIS of the two-electrode coin-cell conguration. In the initial cycles, the impedance values of the Li anode were almost the same, while the impedance values of the LMLO cathode continued to change with an increase in the cycle numbers. This result indicates that the TiO 2−x interlayer mainly benetted the formation of a more conductive CEI at cathode side.

Conclusion
A uniform oxygen-decient TiO 2−x interlayer with controllable thickness was applied to the surface of a commercial Celgard separator for high-performance LMLO cathodes. Compared with the pristine separator, the TiO 2−x interlayer signicantly enhanced the electrochemical performance of the LMLO cathodes. The initial coulomb efficiency, cycle retention aer 100 cycles, and capacity at 5C of the LMLO cathodes increased from 92.1%, 84.2% and 91.3 mA h g −1 to 95.8%, 91.7%, and 203.9 mA h g −1 , respectively. This performance is ascribed to the inhibition of oxygen release and enhancement of electrochemical stability by the TiO 2−x coating layer, which mitigated the side reaction between LMLO and the electrolyte, enhanced the reversibility and inhibited the structural decay of the LMLO  electrode. In addition, the TiO 2−x coating layer prevented oxygen from crossing the separator and favored the formation of a uniform CEI, beneting the cyclability of the cathode electrode. This work provides a novel path to improve the performance of LMLO cathodes using an oxygen-decient TiO 2−x interlayer.

Conflicts of interest
There are no conicts to declare.